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Making Sense of Ethanol and Related Fuels.
The Technical Claims About Ethanol It takes more energy to make than it provides. It turns out that's just not true, even when made from corn. The major factor in those studies which claimed it was a net loss was ignoring the value of the byproducts, which while they won't power cars, can power the refining process, or be used as fertilizer. Ethanol can't be shipped by pipeline. Dirty, rusty water tends to accumulate in pipelines, and the ethanol will soak it up (whereas gas just skips over it). In fact, this is a pretty minor problem; you have to keep your pipelines cleaner, and keeping the ethanol running is a good way to do it. Ethanol is more corrosive than gas, so joints and gaskets have to be made from different materials. Brazil is building an ethanol pipeline, and discussions are underway to build one in this country. Heavy equipment doesn't run on ethanol. Well, little heavy equipment runs on gasoline. You can buy lower end E85 tractors right now, though diesel (and biodiesel) is generally better for heavy equipment. The Environmental Claims About Ethanol Counting production etc. ethanol is no cleaner than gasoline. The basis of this claim is the first claim above - the it takes more energy to produce than it contains. So it's simliarly untrue - even when made from corn by current methods, most studies put it around 15% cleaner. It produces more lower atmosphere ozone. There are two parts to this, and both have some truth. California started adding ethanol to gasoline (at less than 10%) when it turned out that MTBE (an additive that reduces ozone producing pollutants) was poisoning the ground water. It sounded good (pdf warning), because ethanol produces much, much less of one of the ozone forming chemicals (CO). But engines designed to burn gasoline don't fully burn the ethanol, and the partially burned exhaust from such an engine running a low-blend mixture has more of the other two ozone forming chemicals (NOx and VOCs). The problem is especially severe on hot days, which doubles the problem, because the ingredients need to be cooked by the sun to form ozone. The answer seems to be don't feed your gas-burning engine ethanol, especially on hot days. The other part of the story is a study done by Mark Z. Jacobson of Stanford. This is a complex study which claims that ozone pollution from an all E85 fleet may be slightly worse than sticking with gasoline, mainly because of the amount of acetaldehyde and formaldehyde in the exhaust. As inputs he uses emissions projected from current E85 vehicles and software that models the reactions going on in the atmosphere. He finds E85 better in some places, but worse in the NE and LA basin. He himself says of the study: "If you want to use ethanol, fine, but don't do it based on health grounds. It's no better than gasoline, apparently slightly worse." In other words, the findings are not as strong as some have portrayed. I would also point out that currently E85 vehicles are made to take advantage of the economics of ethanol, not the fact that ethanol (at least in theory) burns quite a bit cleaner than gasoline. This would seem to be something to be aware of, and work on, but it's certainly not a showstopper. Indeed, he blames most of the problem on unburned ethanol in the exhaust, the same problem we currently have, and surely more of an engineering problem than a systemic one. (These claims did lead me to look into what people in Brazil have to say. I found some North Americans complaining about pollution in Brazil's cities, but no Brazilians. The main discussion in Brazil seems to be that manual harvesting of sugarcane involves burning the fields, while mechanical harvesting puts a lot of migrant workers out of work.) Large scale ethanol production results in monoculture and reduced biodiversity. True. Large scale farming of any particular plant will do the same. I'll come back to this. Another factor worth noting is the danger of spills. This is one where ethanol is clearly many orders of magnitude less dangerous than oil. How much grass dies when you spill your scotch on the lawn? The Economic and Political Problems of Ethanol The main problem here is that as we try to grow more of our fuel, we put pressure on food prices. Very true. But food production has been subsidized (to the benefit of agribusiness and consumer, not the farmer), and that's been a problem for quite awhile. Growing our fuel just exposes it. It is certainly a big problem with corn, which we feed it to animals that shouldn't eat it, and to ourselves in forms that we shouldn't. Yes, there's a political problem here, and it has nothing to do with what you use the stuff for, just how much you need and the political power that goes with owning all that land. Ethanol can be produced right now from any number of plants - just look at the shelves in the liquor store to see how many choices there are (wheat, corn, rice, potato, barley, grapes, apples...). We are working on ways of producing it from cellulose. We produce methanol (wood alcohol) right now, mostly from otherwise wasted petrochemical by products, but it can be produced from just about any biomass (no new technology needed). Methanol is only slightly more than half the energy content of gasoline (ethanol is about 2/3rds). It sells for about $1.00 / gallon (that price is completely undistorted by subsidies), so except for needing a larger tank, that's like buying gas for $2.00 / gallon (well, OK, nationwide average fuel tax is $0.42 / gallon which isn't in there). Brazil says that ethanol from sugarcane is profitable if oil is above $30 / barrel. Venezuala and Alberta need oil prices above $50 / barrel to be profitable. Including exploration, development and production, Saudi Arabia's cost is $1.50 / barrel. Clearly the market is somewhat distorted. If it takes some subsidizing to break that distortion, it seems like a good investment to me. Yes, the Saudi's will drop the price if they see their oil monopoly threatened. But they can't supply the world anymore, and somewhere around $50 / barrel, they start turning friends into enemies. Alcohol-fueled engines Brazil started on the ethanol route long before flex-fuel vehicles were invented. Gas stations were required to supply both fuels. Two different types of cars were produced, and which ones sold followed oil prices exactly. An alcohol burning engine has higher compression ratio, needs to inject a bit more fuel, sparks later and needs to dissipate more heat. It also needs fuel lines made of materials that can handle the more corrosive fuel. But there aren't ethanol burning engines vs methanol burning engines. An alcohol burning engine burns all of them and any of them. So does a flex-fuel vehicle, (which compromises a bit on compression, but otherwise adjusts to the fuel). Funny how no one tells you that (the 15% gas in E85 is only needed to start the engine - otherwise 100% alcohol is fine). Now that the technology is known, a flex fuel vehicle only costs $100 or $200 more to make. And that is the big advantage of an alcohol (or flex-fueled) vehicle over the gas-guzzler. Whether it's distilled from the finest Champagne grapes or sawdust, the car doesn't care. As they say in Brazil "Drink the best, drive the rest". And that's the ticket out of here. If all the cars on the road are flex-fueled (and interference in the fuel market is minimized), methanol and propanol start competing with various forms of ethanol and gasoline. Moonshining doesn't take the capital investment of an oil refinery. Anyone can do it. A Note on the Writing of this post Most of this was inspired by a talk on BookTV by Robert Zubrin (of Mars exploration fame). I didn't really trust what he had to say, mostly because he is (on this topic) allied with Frank Gaffney (the notorious neocon). So I researched basically every claim he made (found a few to be slightly exaggerated, but nothing surprising for a book talk), then went back and looked at all the objections to ethanol I could find on agonist.org (a number of which Zubrin does not address at all). That said, you will find his arguments here (a review of The Methanol Economy) and here, including the best take-down of the hydrogen boondoggle I have ever seen. Gordon December 27, 2007 - 5:37am
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