Making Sense of Ethanol and Related Fuels.


ear of corn acting as gas pumpI recently reached overload on the number of conflicting claims I'd heard about ethanol, so I went digging. It quickly became obvious that ethanol suffers from both unhinged hype and deranged derision. The answer to the problem as currently framed is a rather unsatisfactory equivocation, but it does point to something far more exciting.

The Technical Claims About Ethanol

It takes more energy to make than it provides. It turns out that's just not true, even when made from corn. The major factor in those studies which claimed it was a net loss was ignoring the value of the byproducts, which while they won't power cars, can power the refining process, or be used as fertilizer.

Ethanol can't be shipped by pipeline. Dirty, rusty water tends to accumulate in pipelines, and the ethanol will soak it up (whereas gas just skips over it). In fact, this is a pretty minor problem; you have to keep your pipelines cleaner, and keeping the ethanol running is a good way to do it. Ethanol is more corrosive than gas, so joints and gaskets have to be made from different materials. Brazil is building an ethanol pipeline, and discussions are underway to build one in this country.

Heavy equipment doesn't run on ethanol. Well, little heavy equipment runs on gasoline. You can buy lower end E85 tractors right now, though diesel (and biodiesel) is generally better for heavy equipment.

The Environmental Claims About Ethanol

Counting production etc. ethanol is no cleaner than gasoline. The basis of this claim is the first claim above - the it takes more energy to produce than it contains. So it's simliarly untrue - even when made from corn by current methods, most studies put it around 15% cleaner.

It produces more lower atmosphere ozone. There are two parts to this, and both have some truth. California started adding ethanol to gasoline (at less than 10%) when it turned out that MTBE (an additive that reduces ozone producing pollutants) was poisoning the ground water. It sounded good (pdf warning), because ethanol produces much, much less of one of the ozone forming chemicals (CO). But engines designed to burn gasoline don't fully burn the ethanol, and the partially burned exhaust from such an engine running a low-blend mixture has more of the other two ozone forming chemicals (NOx and VOCs). The problem is especially severe on hot days, which doubles the problem, because the ingredients need to be cooked by the sun to form ozone. The answer seems to be don't feed your gas-burning engine ethanol, especially on hot days.

The other part of the story is a study done by Mark Z. Jacobson of Stanford. This is a complex study which claims that ozone pollution from an all E85 fleet may be slightly worse than sticking with gasoline, mainly because of the amount of acetaldehyde and formaldehyde in the exhaust. As inputs he uses emissions projected from current E85 vehicles and software that models the reactions going on in the atmosphere. He finds E85 better in some places, but worse in the NE and LA basin. He himself says of the study: "If you want to use ethanol, fine, but don't do it based on health grounds. It's no better than gasoline, apparently slightly worse." In other words, the findings are not as strong as some have portrayed. I would also point out that currently E85 vehicles are made to take advantage of the economics of ethanol, not the fact that ethanol (at least in theory) burns quite a bit cleaner than gasoline. This would seem to be something to be aware of, and work on, but it's certainly not a showstopper. Indeed, he blames most of the problem on unburned ethanol in the exhaust, the same problem we currently have, and surely more of an engineering problem than a systemic one.

(These claims did lead me to look into what people in Brazil have to say. I found some North Americans complaining about pollution in Brazil's cities, but no Brazilians. The main discussion in Brazil seems to be that manual harvesting of sugarcane involves burning the fields, while mechanical harvesting puts a lot of migrant workers out of work.)

Large scale ethanol production results in monoculture and reduced biodiversity. True. Large scale farming of any particular plant will do the same. I'll come back to this.

Another factor worth noting is the danger of spills. This is one where ethanol is clearly many orders of magnitude less dangerous than oil. How much grass dies when you spill your scotch on the lawn?

The Economic and Political Problems of Ethanol

The main problem here is that as we try to grow more of our fuel, we put pressure on food prices. Very true. But food production has been subsidized (to the benefit of agribusiness and consumer, not the farmer), and that's been a problem for quite awhile. Growing our fuel just exposes it. It is certainly a big problem with corn, which we feed it to animals that shouldn't eat it, and to ourselves in forms that we shouldn't. Yes, there's a political problem here, and it has nothing to do with what you use the stuff for, just how much you need and the political power that goes with owning all that land.

Ethanol can be produced right now from any number of plants - just look at the shelves in the liquor store to see how many choices there are (wheat, corn, rice, potato, barley, grapes, apples...). We are working on ways of producing it from cellulose.

We produce methanol (wood alcohol) right now, mostly from otherwise wasted petrochemical by products, but it can be produced from just about any biomass (no new technology needed). Methanol is only slightly more than half the energy content of gasoline (ethanol is about 2/3rds). It sells for about $1.00 / gallon (that price is completely undistorted by subsidies), so except for needing a larger tank, that's like buying gas for $2.00 / gallon (well, OK, nationwide average fuel tax is $0.42 / gallon which isn't in there).

Brazil says that ethanol from sugarcane is profitable if oil is above $30 / barrel. Venezuala and Alberta need oil prices above $50 / barrel to be profitable. Including exploration, development and production, Saudi Arabia's cost is $1.50 / barrel. Clearly the market is somewhat distorted. If it takes some subsidizing to break that distortion, it seems like a good investment to me. Yes, the Saudi's will drop the price if they see their oil monopoly threatened. But they can't supply the world anymore, and somewhere around $50 / barrel, they start turning friends into enemies.

Alcohol-fueled engines

Brazil started on the ethanol route long before flex-fuel vehicles were invented. Gas stations were required to supply both fuels. Two different types of cars were produced, and which ones sold followed oil prices exactly.

An alcohol burning engine has higher compression ratio, needs to inject a bit more fuel, sparks later and needs to dissipate more heat. It also needs fuel lines made of materials that can handle the more corrosive fuel. But there aren't ethanol burning engines vs methanol burning engines. An alcohol burning engine burns all of them and any of them. So does a flex-fuel vehicle, (which compromises a bit on compression, but otherwise adjusts to the fuel). Funny how no one tells you that (the 15% gas in E85 is only needed to start the engine - otherwise 100% alcohol is fine). Now that the technology is known, a flex fuel vehicle only costs $100 or $200 more to make.

And that is the big advantage of an alcohol (or flex-fueled) vehicle over the gas-guzzler. Whether it's distilled from the finest Champagne grapes or sawdust, the car doesn't care. As they say in Brazil "Drink the best, drive the rest". And that's the ticket out of here. If all the cars on the road are flex-fueled (and interference in the fuel market is minimized), methanol and propanol start competing with various forms of ethanol and gasoline. Moonshining doesn't take the capital investment of an oil refinery. Anyone can do it.

A Note on the Writing of this post

Most of this was inspired by a talk on BookTV by Robert Zubrin (of Mars exploration fame). I didn't really trust what he had to say, mostly because he is (on this topic) allied with Frank Gaffney (the notorious neocon). So I researched basically every claim he made (found a few to be slightly exaggerated, but nothing surprising for a book talk), then went back and looked at all the objections to ethanol I could find on agonist.org (a number of which Zubrin does not address at all).

That said, you will find his arguments here (a review of The Methanol Economy) and here, including the best take-down of the hydrogen boondoggle I have ever seen.


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Gordon December 27, 2007 - 5:37am

Instead of investing extensively in ethanol production (either by cellulosic fermentation or cellulosic gasification (a very mature process used to produce methanol)), what would be the net effect of cutting our electric power generation off from the fossil fuel stream to simply burn the cellulose in our generating plant's boilers?

No fancy new experimental conversion plants (Brazil burns excess bagasse to power their sugar extraction from cane), no new pipelines or distribution structure, no subsidies--and a sustainable zero-GHG closed cycle process to produce energy.

The fossil fuels saved (natural gas, coal, oil) can then be turned to powering our SUVs.

As an alternative, let all agricultural and ethanol-production subsidies be eliminated. The government can fund the construction of conversion plants (from corn or cellulose) and end its involvement there. Allow the process to stand and compete on its own merits, or die trying.

There are two big stinking carcasses that most discussions seem to dance around--the per-capita consumption of energy on the part of the industrialized countries and the determination of mankind to be fruitful and multiply.

Petronius December 26, 2007 - 10:23pm

...the bulk of the material. Unless it is very close to the generating plant, the cost of transport negates the benefits.

Of course, that's the same problem that refining ethanol from waste products like wood chips creates. It can't be done on a large scale because the source material must be close to the refinery, and the sheer volume disallows that on a large scale. In the case of wood chips and waste products the material is bulky and not very energy dense.

Corn is a denser product and more easily transported. However, while there is potentially a small increase in the amount of energy produced from corn, most advocates do not include all energy inputs into the equation. As in, the cost of making a tractor, the tires, etc. (When you wear them out, they have to be replaced.)

I did inhale.

Don December 27, 2007 - 6:59am

To understand the effects of biofuel use, the entire lifecycle must be considered, including the manufacture of inputs (e.g. fertilizer), crop production, transportation of feedstock from farm to production facilities, and then biofuel production, distribution, and use.

...

While the six studies compared here are very similar, each uses slightly different system boundaries. To make the results commensurate, we adjusted all the studies so that they conformed to a consistent system boundary. Two parameters, caloric intake of farm workers and farm worker transportation, were deemed outside the system boundaries and were thus set to zero in the adjusted versions. (These factors are very small and the qualitative results would not change if they were included.) Six parameters were added if not reported: embodied energy in farm machinery, inputs packaging, embodied energy in capital equipment, process water, effluent restoration, and coproduct credit.

Gordon December 27, 2007 - 11:20am

They say that even in the dead of a Yellowknife winter, workers at the old Con mine on the edge of the city used to come up from the depths dressed in T-shirts and shorts due to the heat of the bedrock.

Now the northern capital is considering using that heat to extract a different kind of gold from the defunct mine - cheap, greenhouse gas-free energy to warm its buildings on frigid Arctic nights. Early in 2008, Yellowknife will begin studying what could eventually become Canada's first large-scale geothermal heat plant.

``We've got heat resources below our community,'' said Mark Henry, the city's energy co-ordinator. ``We just have to come up with a way to move it.'' Yellowknife is ideally positioned to take advantage of geothermal energy, said Mory Ghomshei, a University of British Columbia engineering professor who's been pushing the idea since 1988.

``We've been working on that for the last 25 years, waiting for the right time and the right place,'' said Ghomshei, who has already completed one report on the project for the city and is expected to bid on a feasibility study.

Geothermal energy is heat created by pressure deep within the earth. Temperatures rise 20 to 30 degrees per kilometre of depth, said Ghomshei, and the Con mine reaches down 2.5 kilometres.
More

adrena December 27, 2007 - 6:48pm

using geothermal for many years and is looking to expand:

http://www.pge.com/news/news_releases/q2_2007/070510a.html

Petronius December 27, 2007 - 8:15pm

the local utility burned mill waste from logging operations to generate electricity and provide steam to heat downtown businesses. But the decline of commercial logging in the Pacific Northwest has doomed the operation, which is now purchasing more power from Bonneville and burning fossil fuels to meet its needs.

But even in its heyday, it was waste chips and bark from the mills that served as fuel. On-site logging waste was piled into huge slash piles and burned in place--just too expensive to haul what's largely water from a mountainside or deep ravine. Consider, for example, that a tree is felled, limbed and bucked high up on a hillside and either carried by suspended cable or dragged using a choker and cable setup to the decking and loading site, leaving the waste where the tree fell.

Some of the larger commercial loggers chip their on-site waste when practical, but leave it to rot. Smaller operations still burn slash piles.

Petronius December 27, 2007 - 8:36pm

It takes more energy to make than it provides. It turns out that's just not true, even when made from corn. The major factor in those studies which claimed it was a net loss was ignoring the value of the byproducts, which while they won't power cars, can power the refining process, or be used as fertilizer.

the energy ratio is still pretty awful. In almost all cases less than 2:1.

I will also note that food production v. demand is dropping precipitously (not sure why, but it seems like it may be climate related) so we may have some severe food problems coming down the pipe. Haven't looked into it in detail yet, but it's something to bear in mind--it's not just about temperature increases, it's about increasingly variable weather patterns, which are doing a real job on a number of key agricultural regions.

It used to be that we had more food than we new what to do with, and all famines were distribution problems. That may not continue to be the case (also because modern agriculture is driven by oil.)

The energy ratio thing matters a lot, btw. If we try and power agriculture by distillation, the numbers just aren't going to work out at that ratio.

(edited to clarify)

Ian Welsh December 27, 2007 - 12:13am

...ethanol. (Except for drinking). It's in favor of good ratios of (dollar value of inputs):(dollar value of outputs) that alcohol fuels can provide (plus the fact that the tech is here now).

(And BTW, the Berkeley study has a good explanation of why the ratios can be deceiving.)

Gordon December 27, 2007 - 12:19am

aren't the only ones that matter. Energy ratios matter more in the long run. You can't run a modern society on 2:1 energy ratios. Ethanol is part of a solution, but imo, it's a small part of it unless you can get a much better ratio.

Ian Welsh December 27, 2007 - 12:21am

Not when all costs are factored in.

I've seen many businesses fail when some accountant tells people how much it costs to operate. In the real world, things cost more to do than estimates suggest. And I am not just talking dollars here. Not all energy inputs are considered in most estimates.

(As an example: in the world of training Thoroughbreds to race, low level trainers are always broke. They figure their expenses. So much for feed. So much for shavings. I pay the groom this much, the gallop boy that much so my cost is this. Then they set their rates. But they forgot that they have to replace tack. That they spend gas driving back and forth from home to work and also hauling horses to the races. Even if they charge for the hauling, they forget that they're wearing out their vehicle. You'll hear--I was doing good until my tires blew out. You wouldn't believe how much it costs...)

However, one overlooked part of the equation for the plus column is that the grain left over after the fermentation process is still valuable as an animal feed, and perhaps even for other uses.

I did inhale.

Don December 27, 2007 - 7:15am

The Berkeley paper (which is basically an examination of 6 other studies, normalizing and recalculating) talks about why ratios are a problem. All of these techniques yield liquid fuel and energy rich solid outputs. Some subtract the solids from the inputs (looks like it makes sense - you can burn it to power the refining), some add it to the outputs, some ignore it (including Pimental - the one who said ethanol was a net loss).

Now try that with switch grass. More solid fuel than liquid (in joules). Subtract it from inputs, you get a negative ratio. Ignore it and you get a terrible ratio. Add it to outputs, and you get like 4:1 or 8:1.

Gordon December 27, 2007 - 11:03am

that's why I front paged it. ;)

Ian Welsh December 27, 2007 - 12:22am

Gordon December 27, 2007 - 11:05am

"It turns out that's just not true, even when made from corn. "

This ignores the cost of dietary substitution and soil erosion. Throw those back in and the present field to fuel solutions are back into net energy deficit, or at LCA's which are worse than growing oats and feeding them to horses.

Biofuels, to be effective as energy enhancers, need to be created by means which don't create competition with growing food, which use far more of the energy in the plant, and which work in sustainable ways. Presently, agri-business based models of growing don't meet these criterion. This isn't an argument against bio-fuels themselves, but againsts our current agricultural production models, which are not workable as sustainable systems in themselves.

Stirling Newberry December 27, 2007 - 10:14am

...(particularly from corn) is that it's here now, and has caused the development of the flex-fuel vehicle. A crappy first step, but if we take it we can leave the crappy part behind. If you don't take it, you're stuck with the crap.

Gordon December 27, 2007 - 11:12am

The elephants in the room are Big Oil, and their big investors (read: Bush Family. Your post talks of 'anyone' producing their own ethanol.

My first thought was this: the Bushies will send American war planes to bomb their own citizens before they will allow citizens to produce their own energy. Controlling energy in the form of oil is so central to everything the Bush and Cheney mafia does, that they will have no qualms about using the entire Budget of the Pentagon and the Intelligence community to fight it.

And if you think Big Oil has put up a fight against alternative fuels and global warmiong, wait until you see the war they will wage when faced with the prospect that Americans don't need them to produce energy.

If Americans start producing their own energy at home with stills, you will see agents busting into American homes and arresting and confiscating on a scale we have never seen before. If citizens try to protect themselves, we will see regular Army troops busting into homes, Iraq-style, and arresting and confiscating, and shooting people sometimes.

Probably, in fact, the Bushies would send in Blackwater to do this kind of work. We all know how that would unfold...

I'm not kidding. If you mess with the Big Oil/Cheney/Bush's oil lifeline, they will kill you.

Whose going to protect you - the Democrats? The DoJ? Ron Paul?

What you are talking about is far too revolutionary for the established powers in the USA today.

yogi-one December 27, 2007 - 10:17am

Stirling mentioned soil erosion above, and this is a truly critical issue that, unfortunately, damns all forms of biofuels as unsustainable on any kind of large scale.

Read this important article on peak soil:

http://www.energybulletin.net/28610.html

As someone has said, there is no such thing as "waste biomass". And as someone else said (I'm having trouble sourcing this quote), the worst thing we could do is burn up the last few inches of our topsoil in our gas tanks.

grassroot December 27, 2007 - 12:00pm

But I don't know why you have to blame biofuels for current agricultural practices. If you eat anything remotely resembling a typical American diet, you are contributing to these problems. We already grossly overuse corn in our own diets and the diets of our livestock.

Pimentel (who is cited by your link) is in favor of reducing the population of the US to 40 to 100 million. Not sure why he doesn't take the obvious step and use the 20+ billion pounds of biomass thus created to generate fuel.

Our dumps, sewers and septic tanks are overflowing with waste biomass.

Gordon December 27, 2007 - 12:44pm

A fuller context for that quote would be, if agriculture and related systems were practiced sustainably, as they one day must be, there will be no such thing as "waste biomass". Particularly in a world without fossil fuel-based fertizers, whatever is not eaten or otherwised used directly must go toward rebuilding the soil.

Clearly we are not anywhere near that point now, and so biofuels from "waste" organic materials do make sense on an interim basis. But even as such, they will not scale up to be a large-scale replacement for fossil fuels.

grassroot December 27, 2007 - 12:59pm

...replacement for fossil fuels right now; we need to compete with fossil fuels. We need to open the door.

We eventually need to replace fossil fuels, but there's no reason it has to be replaced by only one thing (and, of course, we can get a whole lot smarter about how we use energy). Most of the promising technologies are 10 or 15 years out before they get into wide use. And if we keep imagining problems and betting on silver bullets, they'll stay 10 to 15 years out.

Brazil's been doing this for 30 years. They seem to still be with us.

Gordon December 27, 2007 - 1:16pm

In addition to very favorable growing conditions, one of the very significant differences between sugar cane and corn is that cane fixates atmospheric nitrogen:

http://www.p2pays.org/ref/35/34080.pdf

Petronius December 27, 2007 - 6:27pm

that replacing current gasoline consumption in the US with ethanol from corn would mean more than doubling the current total acres of cropland under cultivation. This was assuming that the additional acres would be as productive as the land currently being farmed. This is not a good assumption. The environmental consequences of trying to do this would be severe.

Of course, we shouldn't be feeding corn to livestock; we shouldn't be eating so much meat; yadda, yadda ,yadda. But replacing current gasoline consumption is a huge undertaking and there will be consequences.

I've seen ethanol production in Brazil. It's done with sugar cane, which is much more efficient than corn. And it's done very intensively. The cane is planted so thick that you can't see 3 feet into a field. Some of it is planted on hillsides that are so steep that it looks like it would be quite difficult to walk on them. As you reach the top of a hill, often all you can see for miles is cane planted in fields that come so close to the highway that you can almost reach out the bus window and touch it. It's hard to believe that the soil can withstand this kind of cultivation for very long, especially when the biomass not used for ethanol production is burned in the fermentation process.

Brazillians drive much less per capita than we do. I'm sure they are trying hard to catch up. I hope they don't. Sugar cane production is one of the forces driving the expansion of agriculture into the rain forest. Planetary ecosystem services are being compromised as a result.

If you imagine cities along the Amazon to be lush tropical paradises, forget it. The cities and towns along the (lower) Amazon that I have seen are hot, dusty and treeless (except for some very small rich parts of town.) They are definitely not in danger of being overgrown with tropical vegetation. Once you cut down a clearing in the jungle, you don't have to worry about it growing back.

Beto December 27, 2007 - 2:29pm

and based on a strawman assumption.

Sugarcane doesn't deplete soil. The Native Americans who showed the Puritans how to cultivate corn tried to tell them you can't grow it more than twice before you have to let the land go fallow. The point still hasn't gotten across. It's a terrible crop.

Also pressing on the rainforest: logging, cattle, mining. It used to fashionable to hate Ray Kroc for cutting down rainforests so he could raise beef. Now that honor goes to ethanol, and we hate Ray Kroc for the biodiesel, er, trans-fats in his fries. The more things change...

Gordon December 27, 2007 - 5:43pm

That's because corn is more than just sugar. It contains minerals and protein in addition. Sugarcane is mostly pure sugar but the plant has to contain minerals and protein or it wouldn't grow. Sugar can be made from CO2 from the air but no plant can photosynthesize without iron, magnesium, copper, manganese, fixed nitrogen, etc. When the plant material is harvested and burned the fixed nitrogen and some of the minerals are lost, even if the ash is spread back on the land. And then there are the erosion and compaction issues that inevitably accompany planting and harvesting a crop.

Beto December 27, 2007 - 8:13pm

I read that if all the arable land in the world was used for ethanol production it would only replace half the petroleum we burn.

We already consume all the food the world produces so as acres of land devoted to food production are taken out of production to produce ethanol, more people starve.

Profitable? Yes. To some.

Here's Fidel Castro's take on the subject.

I did inhale.

Don December 27, 2007 - 6:40pm

800 million or so people go hungry. It's not because the world doesn't grow enough food. Just think how rich you'd be if we were anywhere close to the margin.

Gordon December 27, 2007 - 7:24pm

a fifty day supply of wheat world-wide at the moment. The price of wheat on the future's market recently went over $10/bushel.

A drought in the Central US this year and you'll see worldwide famine in '08.

We may be closer to that margin than you expect.

I planted 300 acres of wheat--it's up and growing--but once again, we're getting dry in South Texas. Recently entered stage one drought conditions.

Of course, considerably over half the cultivated land in our region is slated for industrial corn. Farmers farm to fail around here. Pays better than actually growing food. (I guarantee you that if it weren't for subsidies, you'd see very few acres of corn going into the ground considering how dry our soil is. The only large scale farmer I have much respect for has already decided to plant cotton which is much more drought resistant.)

Don December 28, 2007 - 9:33am

...(farming to fail, rescuing obsolete or mismanaged business) get subsidized so consistently and the right things (new ideas, experimentation, conservation) so rarely that I have to believe the political process of providing subsidies is ass-backwards.

Biofuels may well force us to confront the choice of eat-or-drive long before oil does. But that could be a good thing, because by the time oil forces the choice it's too late for either.

Gordon December 28, 2007 - 10:43am

I was also talking only about gasoline, not oil consumption. I'll try to find where I posted that. I did provide sources for my numbers.

Beto December 27, 2007 - 7:50pm

BBC.

Grass biofuels 'cut CO2 by 94%'

Producing biofuels from a fast-growing grass delivers vast savings of carbon dioxide emissions compared with petrol, a large-scale study has suggested.

A team of US researchers also found that switchgrass-derived ethanol produced 540% more energy than was required to manufacture the fuel.

One acre (0.4 hectares) of the grassland could, on average, deliver 320 barrels of bioethanol, they added.

Their paper appears in the Proceedings of the National Academy of Sciences.

The five-year study, involving 10 farms ranging in size from three to nine hectares, was described as the largest study of its kind by the paper's authors.

More at link.

The more flex-fuel cars on the road, the faster this stuff gets to market.

Gordon January 8, 2008 - 11:26am

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